Natural Gas Methane Hydrates

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What are natural gas hydrates?

  • At suitably high pressures and low temperatures, natural gas forms a hydrate with water.
  • Vast reserves of these hydrates have been identified in cold, deepwater environments.
    • Methane hydrate reserves in the range of 300 trillion cubic feed are commonly found.

Where are methane hydrates located?

  • Hydrate layers are often found 300m below the seabed -- trapped between an impervious layer and a layer of water

What are the characteristics of hydrates?

  • Hydrates are metastable compounds that are stable at high pressures and low temperatures.
  • The boundary between free gas and hydrates ranges over a wide range of pressures and temperatures.
    • This range of pressures and temperatures is called the methane hydrate equilibrium.

How are methane hydrate reserves developed?

  • In order to develop a hydrate reserve, the temperature and the pressure of the reservoir have to be adjusted to a position outside the methane hydrate equilibrium.
  • Hydrate reservoir pressure and temperature may be modified in the following ways:

Reduction of hydrate pressure below the hydrate equilibrium pressure

  • This technique requires achieving an extremely large reduction in pressure.
    • Consequently, this technique of hydrate production is viable in only a handful of reserves where the equilibrium pressure is low.

Increase in the reservoir temperature above the hydrate equilibrium temperature

  • This technique is the most practical.

Injection of chemicals to break the hydrate and separate the methane from water

  • This technique is used to prevent the formation of methane hydrates in cold and water-wet environments -- most commonly in gas pipelines.
  • The extremely high cost of this technique makes it unsuitable for methane hydrate field development.

Where have natural gas hydrate resources been discovered?

  1. Black Sea
  2. Blake Ridge
  3. Bush Hill
  4. Costa Rica
  5. Guatemala
  6. Japan Sea
  7. Mexico
  8. Mississippi Canyon
  9. Nankai
  10. Peru
  11. Chile
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